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An antifouling catechol/chitosan-modified polyvinylidene fluoride membrane for sustainable oil-in-water

Shanshan Zhao, Zhu Tao, Liwei Chen, Muqiao Han, Bin Zhao, Xuelin Tian, Liang Wang, Fangang Meng

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1355-5

摘要： Abstract • Underwater superoleophobic membrane was fabricated by deposition of catechol/chitosan. • The membrane had ultrahigh pure water flux and was stable under harsh pH conditions. • The membrane exhibited remarkable antifouling property in O/W emulsion separation. • The hydration layer on the membrane surface prevented oil droplets adhesion. Low-pressure membrane filtrations are considered as effective technologies for sustainable oil/water separation. However, conventional membranes usually suffer from severe pore clogging and surface fouling, and thus, novel membranes with superior wettability and antifouling features are urgently required. Herein, we report a facile green approach for the development of an underwater superoleophobic microfiltration membrane via one-step oxidant-induced ultrafast co-deposition of naturally available catechol/chitosan on a porous polyvinylidene fluoride (PVDF) substrate. Membrane morphology and surface chemistry were studied using a series of characterization techniques. The as-prepared membrane retained the original pore structure due to the ultrathin and uniform catechol/chitosan coating. It exhibited ultrahigh pure water permeability and robust chemical stability under harsh pH conditions. Moreover, the catechol/chitosan hydrophilic coating on the membrane surface acting as an energetic barrier for oil droplets could minimize oil adhesion on the surface, which endowed the membrane with remarkable antifouling property and reusability in a cyclic oil-in-water (O/W) emulsion separation. The modified membrane exhibited a competitive flux of ~428 L/(m2·h·bar) after three filtration cycles, which was 70% higher than that of the pristine PVDF membrane. These results suggest that the novel underwater superoleophobic membrane can potentially be used for sustainable O/W emulsions separation, and the proposed green facile modification approach can also be applied to other water-remediation materials considering its low cost and simplicity.

关键词： Antifouling     Catechol/chitosan co-deposition     Oil-in-water emulsions separation     Underwater superoleophobic    

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Nano-hydroxyapatite formation via co-precipitation with chitosan-g-poly(

Yang YU, Hong ZHANG, Hong SUN, Dandan XING, Fanglian YAO

《化学科学与工程前沿（英文）》 2013年 第7卷 第4期   页码 388-400 doi: 10.1007/s11705-013-1355-0

摘要： With the excellent biocompatibility and osteoconductivity, nano-hydroxyapatite (nHA) has shown significant prospect in the biomedical applications. Controlling the size, crystallinity and surface properties of nHA crystals is a critical challenge in the design of HA based biomaterials. With the graft copolymer of chitosan and poly( -isopropylacrylamide) in coil and globule states as a template respectively, a novel composite from chitosan-g-poly( -isopropylacrylamide) and nano-hydroxyapatite (CS-g-PNIPAM/nHA) was prepared via co-precipitation. Zeta potential analysis, thermogravimetric analysis and X-ray diffraction were used to identify the formation mechanism of the CS-g-PNIPAM/nHA composite and its morphology was observed by transmission electron microscopy. The results suggested that the physical aggregation states of the template polymer could induce or control the size, crystallinity and morphology of HA crystals in the CS-g-PNIPAM/nHA composite. The CS-g-PNIPAM/nHA composite was then introduced to chitosan-gelatin (CS-Gel) polyelectronic complex and the cytocompatibility of the resulting CS-Gel/composite hybrid film was evaluated. This hybrid film was proved to be favorable for the proliferation of MC 3T3-E1 cells. Therefore, the CS-g-PNIPAM/nHA composite is a potential biomaterial in bone tissue engineering.

关键词： chitosan     poly(N-isopropylacrylamide)     hydroxyapatite     coil     globule     bone tissue engineering    

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Lagrangian simulation of deposition of CO gas-solid sudden expansion flow

HUANG Dongping, DING Guoliang, QUACK Hans

《能源前沿（英文）》 2008年 第2卷 第2期   页码 216-221 doi: 10.1007/s11708-008-0032-3

摘要： Freezing and blockage resulting from the deposition of solid CO formed because of sudden expansion of the downstream pipe during the release of CO through safety valves, will endanger the protected equipment. To overcome this problem, the characteristics of the CO gas-solid sudden expansion flow are studied by using the disperse Lagrangian model. A comparison of the calculated deposition of the solid CO with the experimental results shows that they are in reasonable agreement. The simulation results show that the size of the solid CO formed should not be in the range of 0.04–0.07 mm ( number 3.2–9.8). This can be achieved by using an appropriate flow cross section of the safety valve.

关键词： comparison     gas-solid     downstream     blockage     Lagrangian    

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Effect of carbon deposition over carbonaceous catalysts on CH

Yongfa ZHANG, Meng ZHANG, Guojie ZHANG, Huirong ZHANG

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 481-485 doi: 10.1007/s11705-010-0523-8

摘要： An investigation was made using a continuous fixed bed reactor to understand the influence of carbon deposition obtained under different conditions on CH -CO reforming. Thermogravimetry (TG) and X-ray diffraction (XRD) were employed to study the characteristics of carbon deposition. It was found that the carbonaceous catalyst is an efficient catalyst in methane decomposition and CH -CO reforming. The trend of methane decomposition at lower temperatures is similar to that at higher temperatures. The methane conversion is high during the initial of stage of the reaction, and then decays to a relatively fixed value after about 30 min. With temperature increase, the methane decomposition rate increases quickly. The reaction temperature has significant influence on methane decomposition, whereas the carbon deposition does not affect methane decomposition significantly. Different types of carbon deposition were formed at different methane decomposition reaction temperatures. The carbon deposition Type I generated at 900°C has a minor effect on CH -CO reforming and it easily reacts with carbon dioxide, but the carbon deposition Type II generated at 1000°C and 1100°C clearly inhibits CH -CO reforming and it is difficult to react with carbon dioxide. The results of XRD showed that some graphite structures were found in carbon deposition Type II.

关键词： carbon deposition     carbonaceous catalyst     CH4-CO2 reforming    

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Removal of copper by modified chitosan adsorptive membrane

Xiaoshuai LIU, Zihong CHENG, Wei MA

《化学科学与工程前沿（英文）》 2009年 第3卷 第1期   页码 102-106 doi: 10.1007/s11705-009-0123-7

摘要： In this study, a novel adsorptive membrane was prepared from chitosan as the functional polymer and some additive blend solutions by solution casting method. The modified chitosan membrane was characterized by FTIR and its Water Swelling Ratio (WSR). The adsorption of copper ions on the adsorptive membrane was investigated in batch experiments. The results obtained from the experiments indicated that the membrane had a good adsorption capacity for copper ions, the optimal ionic strength and pH were 0.1 and 5-6, respectively. Compared with the Langmuir isotherm model, the experimental data were found to be following the Freundlich model.

关键词： chitosan     adsorptive membrane     copper removal     environmental engineering     heavy metal     isotherm model    

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Dialdehyde cellulose nanocrystal cross-linked chitosan foam with high adsorption capacity for removal

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 853-866 doi: 10.1007/s11705-022-2256-x

摘要： The discharge of large amounts of dye-containing wastewater seriously threats the environment. Adsorbents have been adopted to remove these dyes present in the wastewater. However, the high adsorption capacity, predominant pH-responsibility, and excellent recyclability are three challenges to the development of efficient adsorbents. The poly(acryloxyethyl trimethylammonium chloride)-graft-dialdehyde cellulose nanocrystals were synthesized in our work. Subsequently, the cationic dialdehyde cellulose nanocrystal cross-linked chitosan nanocomposite foam was fabricated via freeze-drying of the hydrogel. Under the optimal ratio of the cationic dialdehyde cellulose nanocrystal/chitosan (w/w) of 12/100, the resultant foam (Foam-12) possesses excellent absorption properties, such as high porosity, high content of active sites, strong acid resistance, and high amorphous region. Then, Foam-12 was applied as an eco-friendly adsorbent to remove acid red 134 (a representative of anionic dyes) from aqueous solutions. The maximum dye adsorption capacity of 1238.1 mg∙g‒1 is achieved under the conditions of 20 mg∙L‒1 adsorbents, 100 mg∙L‒1 dye, pH 3.5, 24 h, and 25 °C. The dominant adsorption mechanism for the anionic dye adsorption is electrostatic attraction, and Foam-12 can effectively adsorb acid red 134 at pH 2.5–5.5 and be desorbed at pH 8. Its easy recovery and good reusability are verified by the repeated acid adsorption–alkaline desorption experiments.

关键词： chitosan foam     cellulose nanocrystals     acid red 134     adsorption    

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Correction to: Highly degradable chitosan-montmorillonite (MMT) nanocomposite hydrogel for controlled

《环境科学与工程前沿（英文）》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1704-2

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Removal of clofibric acid from aqueous solution by polyethylenimine-modified chitosan beads

Yao NIE,Shubo DENG,Bin WANG,Jun HUANG,Gang YU

《环境科学与工程前沿（英文）》 2014年 第8卷 第5期   页码 675-682 doi: 10.1007/s11783-013-0622-0

摘要： Polyethylenimine (PEI)-modified chitosan was prepared and used to remove clofibric acid (CA) from aqueous solution. PEI was chemically grafted on the porous chitosan through a crosslinking reaction, and the effects of PEI concentration and reaction time in the preparation on the adsorption of clofibric acid were optimized. Scanning electron microscopy (SEM) showed that PEI macromolecules were uniformly grafted on the porous chitosan, and the analysis of pore size distribution indicated that more mesopores were formed due to the crosslinking of PEI molecules in the macropores of chitosan. The PEI-modified chitosan had fast adsorption for CA within the initial 5 h, while this adsorbent exhibited an adsorption capacity of 349 mg·g for CA at pH 5.0 according to the Langmuir fitting, higher than 213 mg·g on the porous chitosan. The CA adsorption on the PEI-modified chitosan was pH-dependent, and the maximum adsorption was achieved at pH 4.0. Based on the surface charge analysis and comparison of different pharmaceuticals adsorption, electrostatic interaction dominated the sorption of CA on the PEI-modified chitosan. The PEI-modified chitosan has a potential application for the removal of some anionic micropollutants from water or wastewater.

关键词： clofibric acid     PEI-modified chitosan     adsorption capacity     adsorption mechanism     electrostatic interaction    

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Scaling up of cluster beam deposition technology for catalysis application

《化学科学与工程前沿（英文）》 2021年 第15卷 第6期   页码 1360-1379 doi: 10.1007/s11705-021-2101-7

摘要： Many research works have demonstrated that the combination of atomically precise cluster deposition and theoretical calculations is able to address fundamental aspects of size-effects, cluster-support interactions, and reaction mechanisms of cluster materials. Although the wet chemistry method has been widely used to synthesize nanoparticles, the gas-phase synthesis and size-selected strategy was the only method to prepare supported metal clusters with precise numbers of atoms for a long time. However, the low throughput of the physical synthesis method has severely constrained its wider adoption for catalysis applications. In this review, we introduce the latest progress on three types of cluster source which have the most promising potential for scale-up, including sputtering gas aggregation source, pulsed microplasma cluster source, and matrix assembly cluster source. While the sputtering gas aggregation source is leading ahead with a production rate of ~20 mg·h–1, the pulsed microplasma source has the smallest physical dimensions which makes it possible to compact multiple such devices into a small volume for multiplied production rate. The matrix assembly source has the shortest development history, but already show an impressive deposition rate of ~10 mg·h–1. At the end of the review, the possible routes for further throughput scale-up are envisaged.

关键词： nanoparticle     cluster     cluster beam deposition     magnetron sputtering     heterogeneous catalysis    

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Preparation of Cu/ZrO

Xinmei LIU, Shaofen BAI, Huidong ZHUANG, Zifeng YAN

《化学科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 47-52 doi: 10.1007/s11705-011-1170-4

摘要： Cu/ZrO catalysts for methanol synthesis from CO /H were respectively prepared by deposition coprecipitation (DP) and solid state reaction (SR) methods. There is an intimate interaction between copper and zirconia, which strongly affects the reduction property and catalytic performance of the catalysts. The stronger the interaction, the lower the reduction temperature and the better the performance of the catalysts. Surface area, pore structure and crystal structure of the catalysts are mainly controlled by preparation methods and alkalinity of synthesis system. The conversion of CO and selectivity of methanol are higher for DP catalysts than for SP catalysts.

关键词： Cu/ZrO2     methanol synthesis     deposition coprecipitation     solid state reaction     CO2/H2    

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Bimetallic Ni-Fe catalysts derived from layered double hydroxides for CO methanation from syngas

Honggui Tang, Shuangshuang Li, Dandan Gong, Yi Guan, Yuan Liu

《化学科学与工程前沿（英文）》 2017年 第11卷 第4期   页码 613-623 doi: 10.1007/s11705-017-1664-9

摘要： Carbon deposition and sintering of active components such as nano particles are great challenges for Ni-based catalysts for CO methanation to generate synthetic natural gas from syngas. Facing the challenges, bimetallic catalysts with different Fe content derived from layered double hydroxide containing Ni, Fe, Mg, Al elements were prepared by co-precipitation method. Nanoparticles of Ni-Fe alloy were supported on mixed oxides of aluminium and magnesium after calcination and reduction. The catalysts were characterized by Brunner-Emmett-Teller (BET), X-ray diffraction, hydrogen temperature programmed reduction, inductively coupled plasma, X-ray photoelectron spectroscopy, transmission electron microscopy and thermogravimetric techniques, and their catalytic activity for CO methanation was investigated. The results show that the Ni-Fe alloy catalysts exhibit better catalytic performance than monometallic catalysts except for the Ni4Fe-red catalyst. The Ni2Fe-red catalyst shows the highest CO conversion (100% at 260–350 °C), as well as the highest CH selectivity (over 95% at 280–350 °C), owing to the formation of Ni-Fe alloy. In stability test, the Ni2Fe-red catalyst exhibits great improvement in both anti-sintering and resistance to carbon formation compared with the Ni0Fe-red catalyst. The strong interaction between Ni and Fe element in alloy and surface distribution of Fe element not only inhibits the sintering of nanoparticles but restrains the formation of Ni clusters.

关键词： methanation     layered double hydroxide     bimetal Ni-Fe alloy     sintering     carbon deposition    

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Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1416-4

摘要：

• Solvent-free chitosan oxidation is obtained by rapid mechanochemical reaction.

关键词： Chitosan     High energy ball milling     Mechanochemistry     Oxidation    

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Anthocyanins/chitosan films doped by nano zinc oxide for active and intelligent packaging: comparison

《化学科学与工程前沿（英文）》 2023年 第17卷 第6期   页码 704-715 doi: 10.1007/s11705-022-2270-z

摘要： The multifunctional films was prepared by blending chitosan and nano-ZnO with purple tomato anthocyanins or black wolfberry anthocyanins. The properties of films functioned by anthocyanins source and nano-ZnO content were studied. It was found purple tomato anthocyanins showed more significant color change against pH than black wolfberry anthocyanins. The nano-ZnO were widely dispersed in matrix and enhanced the compatibility of anthocyanins with chitosan. However, the anthocyanins source influenced the properties of the films more slightly than nano-ZnO addition. The tensile strength, antioxidant and antibacterial effects of the chitosan films dramatically increased after cooperated by nano-ZnO and anthocyanins, which also enhanced with increase of nano-ZnO content, whereas the elongation at break of the composite films decreased. Especially, the anthocyanin and nano-ZnO promoted the antibacterial activity of films synergistically. Composite films made from black wolfberry anthocyanins exhibited higher mechanical performance than those made from purple tomato anthocyanins but weaker antibacterial effects. The purple tomato anthocyanins/chitosan and nano-ZnO/purple tomato anthocyanins/chitosan films effectively reflected pork spoilage, changing their colors from dark green to brown, indicating the potential for applications in active and intelligent food packaging.

关键词： bio-based     multifunction     colorimetric indicator     active and intelligent packaging    

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Chitosan/polyethylene glycol impregnated activated carbons: Synthesis, characterization and adsorption

Ehsan Salehi, Fereshteh Soroush, Maryam Momeni, Aboulfazl Barati, Ali Khakpour

《化学科学与工程前沿（英文）》 2017年 第11卷 第4期   页码 575-585 doi: 10.1007/s11705-017-1650-2

摘要： Novel modified activated carbons (ACs) with enhanced adsorptive properties were obtained coating by chitosan (CS), polyethylene glycol (PEG) and blends of the two polymers (0:1, 1:0, 1:1, 1:2 and 2:1 wt/wt) on ACs by an impregnation technique. The adsorption performances of the pristine, acidified and polymer-impregnated ACs were studied using methylene blue as a model adsorbate. The adsorbents were characterized using Fourier transform infrared spectroscopy, scanning electron microscopy and abrasion hardness tests. The average coating thicknesses were between 10 to 23 microns. The pore sizes, pore densities and pore capacities of the activated carbons increased as the wt-% PEG in the coating increased. The highest adsorption capacity (424.7 mg/g) was obtained for the chitosan-coated ACs and this adsorption was well described by the Langmuir isotherm model. The kinetic results were best described by the pseudo-second-order kinetic model. The highest rate constant was obtained with the ACs modified with the CS:PEG (2:1) coating and this result was almost 2.6 times greater than that of the unmodified ACs. The CS/PEG impregnated ACs also displayed superior hardness (~90%), compared to unmodified ACs (~85%). Overall the chitosan had a greater effect on improving adsorption capacity whereas the polyethylene glycol enhanced the adsorption rate.

关键词： carbon biocomposites     impregnation     chitosan     polyethylene glycol     image processing    

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Effective and selective adsorption of uranyl ions by porous polyethylenimine-functionalized carboxylated chitosan

Juan Shen, Fang Cao, Siqi Liu, Congjun Wang, Rigui Chen, Ke Chen

《化学科学与工程前沿（英文）》 2022年 第16卷 第3期   页码 408-419 doi: 10.1007/s11705-021-2054-x

摘要： Composite materials have elicited much interest because of their superior performance in the removal of toxic and radioactive uranyl ions from aqueous solutions. With polyethyleneimine as a functional group, carboxylated chitosan as a matrix, and oxidizing activated carbon as a nanofiller, this study synthesized a novel environment-friendly polyethylenimine-functionalized carboxylated chitosan/oxidized activated charcoal (PCO) biocomposite with a unique three-dimensional porous structure. PCO was synthesized through an easy chemical cross-linking method. Detailed characterization certified the formation of the unique three-dimensional porous structure. The obtained PCO was used to remove uranyl ions from an aqueous solution, demonstrating the maximum adsorption capacity of 450 mg·g . The adsorption capacity of PCO decreased by less than 7.51% after five adsorption-desorption cycles. PCO exhibited good adsorption selectivity ( = 3.45 × 10 mL·g ) for uranyl ions. The adsorption mechanism of PCO was also discussed. The material showed good potential for application in the treatment of wastewater containing uranyl ions.

关键词： polyethylenimine     carboxylated chitosan     activated charcoal     uranyl ion     adsorption    

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标题 作者 时间 类型 操作

An antifouling catechol/chitosan-modified polyvinylidene fluoride membrane for sustainable oil-in-water

Shanshan Zhao, Zhu Tao, Liwei Chen, Muqiao Han, Bin Zhao, Xuelin Tian, Liang Wang, Fangang Meng

期刊论文

Nano-hydroxyapatite formation via co-precipitation with chitosan-g-poly(

Yang YU, Hong ZHANG, Hong SUN, Dandan XING, Fanglian YAO

期刊论文

Lagrangian simulation of deposition of CO gas-solid sudden expansion flow

HUANG Dongping, DING Guoliang, QUACK Hans

期刊论文

Effect of carbon deposition over carbonaceous catalysts on CH

Yongfa ZHANG, Meng ZHANG, Guojie ZHANG, Huirong ZHANG

期刊论文

Removal of copper by modified chitosan adsorptive membrane

Xiaoshuai LIU, Zihong CHENG, Wei MA

期刊论文

Dialdehyde cellulose nanocrystal cross-linked chitosan foam with high adsorption capacity for removal

期刊论文

Correction to: Highly degradable chitosan-montmorillonite (MMT) nanocomposite hydrogel for controlled

期刊论文

Removal of clofibric acid from aqueous solution by polyethylenimine-modified chitosan beads

Yao NIE,Shubo DENG,Bin WANG,Jun HUANG,Gang YU

期刊论文

Scaling up of cluster beam deposition technology for catalysis application

期刊论文

Preparation of Cu/ZrO

Xinmei LIU, Shaofen BAI, Huidong ZHUANG, Zifeng YAN

期刊论文

Bimetallic Ni-Fe catalysts derived from layered double hydroxides for CO methanation from syngas

Honggui Tang, Shuangshuang Li, Dandan Gong, Yi Guan, Yuan Liu

期刊论文

Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

期刊论文

Anthocyanins/chitosan films doped by nano zinc oxide for active and intelligent packaging: comparison

期刊论文

Chitosan/polyethylene glycol impregnated activated carbons: Synthesis, characterization and adsorption

Ehsan Salehi, Fereshteh Soroush, Maryam Momeni, Aboulfazl Barati, Ali Khakpour

期刊论文

Effective and selective adsorption of uranyl ions by porous polyethylenimine-functionalized carboxylated chitosan

Juan Shen, Fang Cao, Siqi Liu, Congjun Wang, Rigui Chen, Ke Chen

期刊论文